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Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.  相似文献   
33.
The experience gained with the current generation of X-ray telescopes like Chandra and XMM-Newton has shown that low energy “soft” protons can pose a severe threat to the possibility to exploit scientific data, reducing the available exposure times by up to 50% and introducing a poorly reproducible background component. These soft protons are present in orbits outside the radiation belts and enter the mirrors, being concentrated towards the focal plane instruments, losing energy along their path and finally depositing their remaining energy in the detectors. Their contribution to the residual background will be even higher for ATHENA with respect to previous missions, given the much higher collecting area of the mirrors, even if the instruments will likely suffer no significant radiation damage from this particles flux. As a consequence this soft proton flux shall be damped with the use of a magnetic diverter to avoid excess background loading on the WFI or X-IFU instruments. We present here a first complete evaluation of this background component for the two focal plane instruments of the ATHENA mission in absence of a magnetic diverter, and derive the requirements for such device to reduce the soft protons induced background below the level required to enable the mission science. We estimate the soft proton flux expected in L2 for the interplanetary component and for the component generated locally by acceleration processes in the magnetotail. We produce a proton response matrix for each of the two instruments of ATHENA focal plane, exploiting two independent Monte Carlo simulations to estimate the optics concentration efficiency, and Geant4 simulations to evaluate the energy loss inside the radiation filters and deposited in the detector. With this modular approach we derive the expected fluxes and spectra for the soft protons component of the background. Finally, we calculate the specifics of a magnetic diverter able to reduce such flux below the required level for both X-IFU and WFI.  相似文献   
34.
In low‐rise steel‐concrete composite structures, moment‐resisting frames can be designed to develop a ductile response in beam‐to‐column joints and column bases by activating flexural yielding of beams and end plates, shear yielding of column web panel zones and yielding of anchors. To evaluate the performance of these components under differing earthquake intensities, a series of pseudodynamic, quasistatic cyclic and vibration tests were carried out on a two‐storey two‐bay moment resisting structure. The performance‐based seismic design and control of these structures requires that stiffness degradation, strength deterioration and slip are properly modelled. In this context, compact hysteretic models can play a key role and must therefore be striven for. Nonetheless, relevant techniques, like nonlinear system identification, are far from representing standard and reliable tools for the dynamic characterization of full‐scale structural systems. With this objective in mind, we present a restoring force surface‐based technique applied to pseudodynamic test data, in view of the nonlinear identification of multistorey frames. The technique is developed by means of a parametric approach, where a time‐variant stiffness operator is coupled to a modified Bouc–Wen model that allows both for slip and for degradation in stiffness. Strength deterioration is indirectly taken into account too. We also show how model‐based parameters can be correlated to the damage process progressively observed both in the structure and in its components. Finally, the predictive capabilities of the identified model are highlighted. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
35.
Using GB-SAR technique to monitor slow moving landslide   总被引:3,自引:0,他引:3  
A Ground-Based SAR (GB-SAR) interferometer was employed to measure the surface displacements of a landslide occurring in the Carnian Alps, north-eastern Italy, which has affected a national road and seriously damaged a road tunnel still under construction. Moreover, since the landslide is located on the left bank of the Tagliamento River Valley, it is feared that this mass movement might dam the river, creating a basin that would increase natural hazard for the valley inhabitants. The data collected from December 2002 to July 2005 by a conventional monitoring system, consisting of a GPS network and boreholes equipped with inclinometric tubes, showed that the landslide was moving at a quasi-constant rate of about 3 cm per year. Due to the slow deformation rate of the landslide, a recently developed GB-SAR technique based on the analysis of a restricted ensemble of coherent points was used. Two surveys, each lasting two days, were planned in December 2004 and July 2005, in order to map and measure the surface displacements that occurred over time. The results from the radar were compared with the ones derived from the GPS monitoring network. An agreement was achieved among the data collected, showing the capability of the GB-SAR technique to measure displacements even within a time span of several months between the surveys.  相似文献   
36.
Abstract. Samples of Mytilus galloprovincialis and Mullus barbatus were collected in eight coastal sites along the South Adriatic and Ionic coasts of Italy in spring 2000 for a survey of coastal pollution in the Mediterranean basin. Specimens were analysed using an integrated approach based on residue analysis of common aquatic pollutants like organochlorines such as hexachlorobenzene (HCB), DDTs and polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), heavy metals and nonylphenols (NPnE) and biomarker responses such as acetylcholinesterase (AChE) activity, and the two specific P450 activities benzo(a)pyrene monooxygenase (BPMO) and 7-ethoxyre-sorufin-(9-deethylase (EROD). Biological and morphological parameters like somatic liver index (SLI), gonadosomatic index (GSI) and gonadal and gamete histology (eggs and sperms) were also evaluated in red mullet samples. A contamination gradient in which several hot spots occur were revealed in this study. The hot spots account for high levels of organochlorines in both species near incinerators and of PAHs in harbour areas. Levels of both NPnE and AChE activity were highest in two protected marine areas and were within detectable limits in others. This finding was confirmed by P450 activities, in which maximum levels were detected in harbours and protected marine areas. No morphological alterations of male and female gonads were observed on the histological level.  相似文献   
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Observations of the solar corona in the FeXIV 530.3 nm “green line” have been very important in the past, and are planned for future coronagraphs on-board forthcoming space missions such as PROBA-3 and Aditya. For these instruments, a very important parameter to be optimized is the spectral width of the band-pass filter to be centred over the “green line”. Focusing on solar eruptions, motions occurring along the line of sight will Doppler shift the line profiles producing an emission that will partially fall out of the narrower pass-band, while broader pass-band will provide observations with reduced spectral purity. To address these issues, we performed numerical (MHD) simulation of CME emission in the “green line” and produced synthetic images assuming 4 different widths of the pass-band (Δλ = 20 Å, 10 Å, 5 Å, and 2 Å). It turns out that, as expected, during solar eruptions a significant fraction of “green line” emission will be lost using narrower filters; on the other hand these images will have a higher spectral purity and will contain emission coming from parcels of plasma expanding only along the plane of the sky. This will provide a better definition of single filamentary features and will help isolating single slices of plasma through the eruption, thus reducing the problem of superposition of different features along the line of sight and helping physical interpretation of limb events. For these reasons, we suggest to use narrower band passes (Δλ ≤ 2 Å) for the observations of solar eruptions with future coronagraphs.  相似文献   
39.
Background has played an important role in X-ray missions, limiting the exploitation of science data in several and sometimes unexpected ways. In this presentation I review past X-ray missions focusing on some important lessons we can learn from them. I then go on discussing prospects for overcoming background related limitations in future ones.  相似文献   
40.
Surface sediment from 15 Italian marine protected areas (MPA) were analysed for polycyclic aromatic hydrocarbons (PAHs). The organic carbon percentage was also determined. Total PAH concentrations (ng g−1 d.w.) ranged from 0.71 (Penisola del Sinis) to 1550 (Miramare). Individual PAH analysis showed that three and four rings PAHs were the most frequently detected isomers and accounted for 60-70% of the PAH total concentrations. PAH ratio analysis showed a prevalence of pyrolytic PAH origin at most of the MPAs with exception of Porto Cesareo and Ustica where a petrogenic origin was detected. Results for organic carbon percentages ranged from 0.3% (Capo Rizzuto) to 2% (Punta Campanella). These results are comparable to other Mediterranean marine environments. However, our results shows that some MPAs, such as Miramare, Porto Cesareo, Isola Capo Rizzuto and Punta Campanella, are subject to strong pressure from urban and industrial activities where high PAH levels were detected.  相似文献   
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